联系方式
李辉林,教授,硕士生导师。2015年博士毕业于兰州大学,师从于厍学功教授。先后在香港科技大学化学系(合作导师:孙建伟教授)和新加坡国立大学化学系(合作导师:卢一新教授)从事博士后研究。2018年6月,全职回国,加入兰州大学化学化工学院,功能有机分子化学国家重点实验室工作。李辉林博士目前的研究兴趣为天然产物全合成和有机合成方法学。
国家自然科学基金青年项目1项和面上项目1项
近5年代表性论文(Representative Publications):
1. Total Synthesis of the Euphorbia Diterpenoid Pepluacetal; Meng Liu, Chuanhua Wu, Xingang Xie, Huilin Li*, Xuegong She* , Angew. Chem. Int. Ed. 2024,e202400943.
2. Rearrangement of the Tetra- and Tricyclic Skeletons of Pepluanol B to Access the Core Structures of Tigliane- and Myrsinane-Type Euphorbia Diterpenes; Chuanhua Wu, Jing Zhang, Meng, Liu, Huilin Li*, Xuegong She*, Org. Lett. 2023, 25, 7995−7999.
3. Direct bromoalkoxylation of enones under acid-free conditions; Bowen Fang*, Lele Zhai, ZHongqin Li, Huilin Li*, Tetrahedron Lett. 2023, 126, 154647.
4. De Novo Diastereoselective Synthesis of 1‑Hydroxyl Allogibberic Methyl Ester en Route to Diverse Bioactive Molecules; Jinyan Chen, Yunxia Yang, Chuanhua Wu, Liang Huo, Xingang Xie, Huilin Li*, Xuegong She* , Org. Lett. 2022, 24, 6402−6406.
5. Organoborane-catalyzed selective 1,2-reduction of alkynones with hydride transfer: Synthesis of benzyl alkynes; Lele Zhai, Zhigang Yang, Qinghong Man, Mingyu Yang, Yangqing Ren, Lei Wang, Huilin Li*, Xuegong She, Tetrahedron Lett. 2022, 91, 153645.
6. Catalyst-Free 1,2-Dibromination of Alkenes Using 1,3-Dibromo-5,5-dimethylhydantoin (DBDMH) as a Bromine Source; Lei Wang, Lele Zhai, Jinyan Chen, Yulin Gong, Peng Wang, Huilin Li*, and Xuegong She, J. Org. Lett. 2022, 87, 3177-3183.
7. Solvent-free, B(C6F5)3-Catalyzed S−H Insertion of Thiophenols and Thiols with α-Diazoesters; Peng Wang, Yulin Gong, Xiaoyu Wang, Yangqing Ren, Lei Wang, Lele Zhai, Huilin Li,* Xuegong She, Chem. Asian J. 2022, 17, e202200465.
8. The Total Synthesis of Diquinane-Containing Natural Products; Huilin Li*, Jing Zhang, Xuegong She*, 2021, 27, 4839-4858. (Frontispiece)
9. Total Synthesis of (−)‐Pepluanol B: Conformational Control of the Eight‐Membered‐Ring System;Jing Zhang, Meng Liu, Chuanhua Wu, Gaoyuan Zhao, Peiqi Chen, Lin Zhou, Xingang Xie, Ran Fang, Huilin Li,* Xuegong She,* Angew. Chem. Int. Ed. 2020, 59, 3966-3970.
10. Pd‐Catalyzed ortho‐C−H Olefination of Benzenesulfonamides Directed by 7‐Azaindole; Xing Huo*, Jun Han, Xiaoxiao Yan, Heng Zhang, Juan Xiong, Jian Liu, Xiaolei Wang, Huilin Li*, Leiming Huo* , Asian J. Org. Chem. 2020, 9, 2087-2091.
11. Enantioselective Construction of All‐Carbon Quaternary Stereogenic Centers by Using Phosphine Catalysis; Huilin Li, Yixin Lu*, Asian J. Org. Chem. 2017, 6, 1130-1145.
12. Catalytic Enantioselective Aza‐Piancatelli Rearrangement; Huilin Li, Rongbiao Tong, Jianwei Sun*, Angew. Chem. Int. Ed. 2016, 55, 15125-15128.
承担本科生基础有机化学实验和课程教学