联系方式
韩丙,男,理学博士,教授,博士生导师。2000年毕业于西北师范大学化学化工学院,获得学士学位。2006年7月毕业于兰州大学化学化工学院有机化学专业,获得博士学位。同年赴美国休斯敦大学化学系跟随美国国家科学院院士Jay K. Kochi教授从事物理有机化学博士后研究工作。2008年1月回到兰州大学功能有机分子化学国家重点实验室工作。2013年入选教育部“新世纪优秀人才支持计划”,2014年获得国家自然科学基金委优秀青年基金资助。迄今已经在国际学术期刊Angew. Chem. Int. Ed., Chem Commun., Org. Lett., J. Org. Chem., Cryst. Growth Des.等上发表论文30余篇。
科研项目:
● 2015/01–2017/12,自由基化学,国家自然科学基金委优秀青年基金,(21422205、主持在研);
● 2013/01–2016/12,肟自由基和腙自由基参与的有机反应研究及其在合成中的应用,国家自然科学基金委面上项目,(21272106、主持在研)
近期代表性论文:
1. Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals, Duan, X.-Y.; Zhou, N.-N.; Fang, R.; Yang, X.-L.; Yu, W.; Han, B.* Angew. Chem. Int. Ed. 2014, 53, 3158–3162.
2. Iminoxyl Radical-Promoted Dichotomous Cyclizations: Efficient Oxyoximation and Aminooximation of Alkenes, Peng, X.-X.; Deng, Y.-J.; Yang, X.-L.; Zhang, L.; Yu, W.; Han, B.* Org. Lett. 2014, 16, 4650?4653.
3. Synthesis of Isoxazoline-Functionalized Phenanthridines via Iminoxyl Radical-Participated Cascade Sequence, Yang, X.-L.; Chen, F.; Zhou, N.-N.; Yu, W.; Han, B.* Org. Lett. 2014, 16, 6476?6479.
4. Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines, Duan, X.-Y.; Yang, X.-L.; Fang, R.; Peng, X.-X.; Yu, W. Han B.* J. Org. Chem. 2013, 78, 10692–10704.
5. Oxime Radical Promoted Dioxygenation, Oxyamination and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones, Han, B.*; Yang, X.-L.; Fang, R.; Yu, W.; Wang, C.; Duan, X.-Y.; Liu, S. Angew. Chem. Int. Ed. 2012, 51, 8816-8820. (Hilighted by Chin. J. Org. Chem. 2012, 32, 2198)
6. CuCl/DABCO/4-HO-TEMPO-Catalyzed Aerobic Oxidative Synthesis of 2-Substituted Quinazolines and 4H-3,1-Benzoxazines, Han B.*; Yang, X.-L.; Wang, C.; Bai, Y.-W.; Pan, T.-C.; Yu, W.* J. Org. Chem. 2012, 77, 1136–1142.
7. Efficient Aerobic Oxidative Synthesis of 2-Aryl Quinazolines via Benzyl C–H Bond Amination Catalyzed by 4-Hydroxy-TEMPO, Han, B.*; Wang, C.; Han, R.-F.; Yu, W.*; Duan, X.-Y.; Fang, R.; Yang X.-L. Chem. Commun. 2011, 47, 7818–7820. (Highlighted by Synfacts, 2011, 9, 0942–0942)
8. Ma, L.; Wang, X.; Yu, W. *; Han, B.*, TBAI-Catalyzed Oxidative Coupling of Aminopyridines with β-Keto Esters and 1,3-Diones—Synthesis of Imidazo[1,2-a] pyridines, Chem. Commun. 2011, 47, 11333–11335.